What Is Glassine?
Unlike its name, glassine is not glass – but it does have some glasslike features. Glassine is a pulp-based material that has been mistaken for other substrates, such as wax paper, parchment, even plastic. Because of its unique look and feel, it may not seem like regular paper. And it’s not! Let’s take a closer look at glassine’s manufacturing process to see how each step contributes to the final product.
What is Glassine?
When you think of paper, transparency may not immediately come to mind. But glassine is a smooth, glossy paper that is transparent. Glassine allows what’s inside or behind the paper to show through. As a result of the manufacturing process, glassine is pH neutral and acid free. And it’s resistant to moisture, air, and grease. Because it is made from wood pulp, glassine is fully recyclable and biodegradable – making it a sustainable material choice.
From trees to pulp to paper.
Glassine is made from hardwood trees, primarily varieties of aspen, oak, birch, and gum. Once the trees are grown to a specific size, the virgin timber is felled, stripped of its branches and twigs, and cut for transport. When logs arrive at the paper mill, they are completely debarked and sent to chippers, where they are cut into pieces for mechanical or chemical pulping.
The first step in the papermaking process is converting the trees into pulp (the fibrous raw material used to make paper). The pulping process cooks the wood chips under pressure in a variety of ion solutions to break the chemical bond of the lignin (the organic polymers that form the cell walls and support tissue in plants). This process separates the pure cellulose fibers from the lignin and other substances.
Removing all of the lignin from the fiber during the pulping process is a crucial step in making glassine paper. If lignin remains in the pulp during bleaching, the chemical reaction with the bleach turns the lignin into hydrochloric acid, which can make the paper brittle and discolored over time. By removing the lignin, the pulp produces a paper with a neutral pH level and higher resistance to changes in chemical, structural, or optical properties. These properties are what make glassine so unique.
The wood fibers that remain are now ready to be bleached and treated further with dyes, pigments, or additives to fit the desired grade and color before moving on to the paper machine. There, the watery pulp slurry flows onto a moving wire cloth where most of the water drains through. The fibers mat and intertwine as paper sheets begin to take form. More of the water is squeezed from the damp mat as it passes through a series of roller presses. And finally through the dryer section of the papermaking machine.
The supercalendering process.
Calendering is the final step in the papermaking process. This smooths the surface of the paper by pressing it between hard pressure cylinders or rollers — called calendars.
Source: AAE Intec. “Calendering.” Reference Document for the Production of Pulp, Paper and Board, Matrix of Industrial Process Indicators, 8 Aug. 2016
Glassine gets its uniquely smooth, transparent, and glossy properties through a process called supercalendering. This process is completed by putting the paper through the calendaring process multiple times or, more often, by performing the pressing on a special machine with heated or cooled pressurized calendars.
Supercalendering machines are specifically designed to apply pressure, heat, and friction at high speeds through vertical, alternating stacks of hard polished steel rollers paired with softer fiber-covered cylinders (called nips). As the high-speed calenders spin, the soft rolls struggle to return to their original dimensions and buff the paper passing through the nips. The force generated by each progressive nip polishes both surfaces of the paper.
At a cellular level, the supercalendering process breaks down the capillaries of the paper fibers. This gives the paper a highly closed surface with improved density and very low porosity. As a result, supercalendaring makes glassine resistant to grease, air, and moisture – ideal barrier protection from many substances.
Many papers contain wax coatings or plastic laminates to achieve these protective benefits. Plastic fragments and silicone coatings are typically less biodegradable. Free from waxes or coatings, glassine is a sustainable alternative to laminated counterparts.
Once the glassine paper completes its journey through the supercalendering machine, it is rolled or sheeted. Glassine sheets are often used for interleaving, inserting specific-sized sheets between delicate artwork, documents, books, or photos to protect from damage. Sheets are also used for windowing of envelopes and manufacturing fully translucent envelopes.
How glassine gets its unique appearance.
Glassine is used most often in its translucent form because it shows what is beneath the paper. The color can be changed during the pulping process with the addition of dyes. Other additives – such as clay, titanium dioxide, or calcium carbonate – reduce the amount of light that is transmitted through the paper and make glassine more opaque.
The degree and quality of the supercalendering machine impacts how dense, and in turn how translucent, the final product becomes. The quality can vary drastically among manufacturers, with the clarity usually lost in cheaper glassine paper.
Adjustments in the supercalendering process determine the weight, caliper (thickness), clarity, brightness, smoothness, strength, and grade of the final product.
- Glassine’s significantly higher density and caliper give it greater bursting and tensile strength, folding endurance, and stiffness than papers of similar weight. Glassine is generally available in densities between 40–90 grams per square meter (gsm) – more than twice as dense as other common papers.
- Glassine is manufactured within a narrow caliper tolerance, meaning measurements of the thickness are highly accurate to within 0.01 millimeters.
- Paper typically absorbs water vapor from the surrounding atmosphere (hygroscopicity), which causes it to expand or contract with the relative humidity (hygroexpansivity). However, the breakdown of cellulose during the manufacturing process of glassine makes it less susceptible to atmospheric changes.
- High quality glassine is hardwearing, making it a robust choice for enclosures and packaging
Converting glassine – from printing to finishing.
Glassine’s surface is suitable for rotogravure, offset, flexo, and digital printing. Supercalendaring renders glassine paper less porous, which means lower levels of ink absorption, making it more difficult to print. Because inks take longer to dry, smearing during or after printing is a concern. Printing on glassine requires both expertise and experience with printing processes and a variety of inks, especially to achieve fine-line images in vivid, full color.
Glassine can be embossed and debossed to create impactful three-dimensional effects. But because of its body and smooth surface, glassine paper tends to shift and crinkle, making embossing difficult. Finishing glassine requires expertise in machine modifications and strategically adjusting guides and tensions.
How glassine is different from related products.
Very few materials offer the widespread benefits of glassine – all in one substrate. While glassine has been confused with other substrates, such as wax paper and parchment, it really is one of a kind. It protects against grease, water, air, and moisture. It’s approved for direct food contact. It can be safely sterilized. And most importantly, glassine can help lower your environmental footprint. Free from coatings or dyes, glassine is fully recyclable and biodegradable.
See how other products compare:
Vellum dates back hundreds of years. It was originally used to describe papers made through the tanning process from calfskin by stretching, drying, and refining it until it became very thin and slightly translucent. Today vellum defines a type of finish or surface structure for uncoated commercial printing papers. It is commonly used to describe all translucent papers. Along with its translucent quality, true vellum paper has a distinctive toothy or slightly rough surface, which contrasts with glassine’s smooth feel. And unlike glassine’s relative strength and durability, vellum is considerably more delicate and can be easily punctured or torn.
Parchment Paper is a cellulose-based paper that has been chemically treated and infused with silicone to create a non-stick surface. This surface is both water- and heat-resistant up to 420°F. Because of the coating, parchment paper is reusable but not recyclable or compostable. And unlike glassine, parchment paper is difficult to print or adhere labeling.
Wax Paper is coated with a thin layer of paraffin or soybean-based wax. The coating makes it non-stick and water resistant, but not heat resistant. Wax paper is often used for the presentation and storing of food. It is not safe to be used in ovens because it will smoke, melt, or even ignite. The wax coating applied to the paper takes much longer to biodegrade. As a result, wax paper is not considered recyclable or compostable. Wax paper is also difficult to print or adhere to.
Cellophane is a completely transparent film that looks like plastic – but it’s actually cellulose that has been removed from wood, hemp, cotton, or another plant source. Cellophane is resistant to oil, grease, and water vapor, but is so thin that it is vulnerable to liquids. Cellophane’s manufacturing process is not eco-friendly because it uses toxic chemicals (such as carbon disulfide) to remove elements and soften and bleach the cellulose. These chemicals could release methane if lodged in a landfill.
JBM is leading glassine packaging innovations – glassine envelopes, bags, and sheets.
At JBM, we specialize in glassine. For more than 15 years, we’ve manufactured billions of glassine bags and envelopes. We have invested years of research into creating the ideal glassine packaging solutions. And our Innovation Team tested multiple inks and printing processes to balance the difficulties of printing on glassine paper. From stamp collecting and sterilized surgical needles to chocolate wrappers and soaps, customers have successfully used JBM’s custom printed glassine envelopes, pouches, and bags across industries in numerous applications.
